Journal
RSC ADVANCES
Volume 6, Issue 29, Pages 23987-23994Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra03798d
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- Ranbaxy Laboratories Pvt. Ltd. (India)
- CSIR, New Delhi, India
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A novel regioselective synthesis of 2-aminoquinolines and 2-arylquinoline-3-carbonitriles is described via copper-mediated tandem reaction. Formation of substituted quinolines involves Knoevenagel condensation of ortho-bromobenzaldehyde with active methylene nitriles followed by copper-catalyzed reductive amination and intramolecular cyclization.
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