Journal
RSC ADVANCES
Volume 6, Issue 64, Pages 59016-59020Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra11791k
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Funding
- Russian Foundation for Basic Research (RFBR) [15-03-05546]
- Russian Science Foundation (RSF) [14-50-00126]
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A facile synthetic approach to photoactive diarylethenes comprising a cyclopentene ring as an ethene bridge was developed based on reduction of 2,3-diaryl(hetaryl)cyclopent-2-en-1-ones through an ionic hydrogenation reaction. The method provides access to unsymmetrical photoswitchable diarylethenes containing benzene, thiophene, or azoles (thiazole, oxazole, imidazole) as aromatic moieties in 40-71% yields. Diarylethenes comprising two heterocyclic moieties show typical photochromic properties, with absorption maxima of the photoinduced form in the blue region (yellow photochromes).
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