Journal
RSC ADVANCES
Volume 6, Issue 71, Pages 67150-67156Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra11838k
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Funding
- CSIC
- ANII
- PEDECIBA
- [ANII-FSE-1-2011-1-6458]
- [EQC-X-2012-1-14]
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In this report, we study the effect of the addition of fluorine-free 2,2'-bis(4,5-dimethylimidazole) (BDI) on lithium-ion solid polymer electrolytes based on lithium nitrate and poly(methyl methacrylate) (PMMA). Confocal Raman spectroscopy and theoretical Raman calculations were performed to study lithium dissociation and the interaction mechanism of the lithium and nitrate ions with the BDI additive. Additionally, X-ray diffraction analysis showed that the mean coherence length of the PMMA chains is influenced by the BDI concentration. The incorporation of the BDI additive favors the dissociation of lithium salt leading to a maximum enhancement on the lithium conductivity of up to 1.88 x 10(-4) S cm(-1) for a critical BDI addition of similar to 5% with respect to PMMA, which is very high in comparison with the conductivities of similar to 10 (4) S cm (1) usually observed for these solid polymer electrolytes.
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