Journal
RSC ADVANCES
Volume 6, Issue 71, Pages 67226-67231Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra14365b
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Funding
- National Natural Science Foundation of China [51503016]
- Fundamental Research Funds for the Central Universities [FRF-TP-15-001A2]
- Key Laboratory of Photochemical Conversion and Optoelectronic Materials, TIPC, CAS
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A novel Bronsted acid derived metal-organic framework (MOF) has been developed to serve as an efficient heterogeneous catalyst for the acetalization and Morita-Baylis-Hillman reaction. Aromatic sulfonic acid groups were successfully incorporated to the framework of UiO-66 by post-synthetic modifications using commercially available anhydridic reagents. The UiO-66-RArSO3H Bronsted acid catalyst was fully characterized using SEM, PXRD, FTIR, TGA and N-2 adsorption/desorption isotherms. Furthermore, efficient acetalization and Morita-Baylis-Hillman reactions were evaluated to demonstrate the high catalytic performance of the UiO-66-RArSO3H catalyst. The UiO-66-RArSO3H catalyst is compatible with a variety of substituted substrates and can be recycled five times without a compromise in the yield or selectivity.
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