RuV(NCN-Me)(bpy)(=O)]3+ mediated efficient photo-driven water oxidation

The [Ru(NCN-Me)(bpy)H2O](PF6)(2) complex (1) (where NCN-Me is the neutral N-methyl-3,5-di(2-pyridyl) pyridinium iodide after deprotonation of the C-H bond) acts as an active catalyst for the visible light driven oxidation of water, when employed with [Ru(bpy)(3)](2+) as the photosensitizer and Na2S2O8 as the sacrificial electron acceptor in a phosphate buffer solution at pH 6.5, in the presence of a visible light emitting diode (LED; visible light 10.2 mW cm(-2)) at 20 degrees C. The system exhibits very high activity, achieving 130 turnovers with respect to catalyst and an initial turnover rate TOF of 0.10 s(-1). The controlled experiments conducted for the photo-oxidation of water indicate that the catalytic system is dependent upon the following: (i) a visible light source, (ii) photosensitizer, (iii) catalyst and, (iv) pH. During the photocatalysis of water oxidation for 2 h in a phosphate buffer solution at pH 6.5, there was no degradation of the catalyst 1, which indicates the good photo-stability of the complex. The NCN-Me coordinates as a neutral ligand after deprotonation of the central C-H bond; generating the negatively charged carbon center favors a reduction in the redox potential of the complex, which considerably lowers the overpotential to 100 mV at pH 6.5 for the oxidation of water.