Journal
RSC ADVANCES
Volume 6, Issue 27, Pages 22653-22658Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra00374e
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Funding
- Program of National Natural Science Foundation of China [41322037, 41130858]
- Program of Natural Science Foundation of Shandong Province of China [JQ201510]
- Marine Special Public Welfare Scientific Research, State Oceanic Administration of China [201405038]
- Taishan Scholars Program, China
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Marine life forms are an important source of structurally diverse and biologically active natural products. As a unique case of both enantiomeric and atropisomeric isomers being present in one marine natural product structure, two new dichlorinated diphenylmethanes containing both point and axial chirality, (+/-)-pestalachlorides E (1) and F (2), were isolated from a marine-derived Pestalotiopsis (ZJ-2009-7-6) fungus. Both of them showed potent antifouling activities against the larval settlement of the barnacle Balanus amphitrite at nontoxic concentrations with EC50 values of 1.65 and 0.55 mu g mL(-1), respectively, and antifouling activity was detected for the first time for this class of metabolites.
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