4.6 Article

A new application of the traditional Fenton process to gold cyanide synthesis using acetonitrile as a cyanide source

Journal

RSC ADVANCES
Volume 6, Issue 20, Pages 16448-16451

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra01025c

Keywords

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Funding

  1. CFI
  2. NSERC
  3. NRC
  4. CIHR
  5. University of Saskatchewan
  6. Government of Saskatchewan
  7. Western Economic Diversi-fication Canada
  8. NSFC [21222307, 21373181, 21403197, 21503189]
  9. Fundamental Research Funds for the Central Universities [2014XZZX003-02]
  10. Zhejiang Provincial Natural Science Foundation of China [LY15B030009]
  11. China Postdoctoral Science Foundation [2014M550333, 2015T80636]

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Previous cyanation processes always involved the use of hypertoxic CN- ions or UV-light, which is health-risky and energy-wasting. For the purpose of environment-friendly chemistry, we introduced a general Fenton-reaction synthesis of metal cyanide solids using acetonitrile as a green cyanide source. This Fenton-improved cyanation method gets rid of CN- ions and UV-light efficiently, which is green and facile.

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