Journal
RSC ADVANCES
Volume 6, Issue 18, Pages 14559-14562Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra23683e
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Funding
- Wuhan University [203273463, 203410100064]
- 111 Project of the Ministry of Education of China
- National Natural Science Foundation of China [21372179, 21432007, 21502145]
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We successfully developed new tetraphosphite ligands L1-L5 and applied them to the rhodium-catalyzed hydroformylation of terminal and internal olefins. High catalytic reactivities and excellent regioselectivities for linear aldehydes were obtained in the rhodium-catalyzed hydroformylation of simple olefins (l/b ratio up to 90, 98.9% linear selectivity, 99.2% conversion) using the tetraphosphite ligand L2. And the tetraphosphite ligand L2 also displayed moderate to good linear regioselectivities for challenging substrates styrene and internal olefin 2-octene.
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