4.6 Article

Sustainable carbon-sheets and their MnO-C hybrid for Li-ion batteries

Journal

RSC ADVANCES
Volume 6, Issue 82, Pages 79066-79071

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra15411e

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Funding

  1. National Basic Research Program of China (973 Program) [2013CB934001]
  2. National Natural Science Foundation of China [51274017]
  3. National 863 Program of China [2013AA050904]
  4. International S&T Cooperation Program of China [2012DFR60530]
  5. Shanghai Academy of Space Technology [SAST201467]
  6. Academic Excellence Foundation of BUAA

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The future development of large-scale energy store systems requires Li-ion batteries (LIBs) with not only an outstanding electrochemical performance but also sustainability and cost-effectiveness. Herein, unique carbon-sheets (CSs) with rich porosity and high graphitization have been synthesized from sugarcane-stalk for LIBs application. These derived CSs exhibit a superior electrochemical behavior to commercial graphite. Moreover, the performance of CSs can be further upgraded by growing MnO nanoparticles to form a synergetic MnO-C hybrid. As a result, the MnO-C hybrid shows a high capacity, excellent rate capability (354mA h g(-1) at 3 A g(-1)), and superior cycling performance (814 mA h g(-1) at 0.2 A g(-1) after 400 cycles).

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