Journal
RSC ADVANCES
Volume 6, Issue 5, Pages 3561-3570Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra25910j
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Funding
- China University of Geosciences (Wuhan) [CUGL090223]
- National High-Tech R&D Program (863 program) [SQ2010AA1000690005]
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The self-assembly technique provides a new and simple route for designing porous hydrogels. At present, most of the studies in graphene oxide (GO)-polymer hydrogels are concentrated on mechanical reinforcement. Developing a self-assembled GO-based porous hydrogel along with swelling and mechanical merits is still challenging, yet very interesting and desirable for practical applications. Herein, we report self-assembled GO-based macroporous composite hydrogels by integrating GO sheets and chitosan-based hydrogel networks. GO sheets, containing adequate hydrophilic functional groups, can be dispersed well and thereby they form self-assembled supramolecular structures with polymer chains by effective intermolecular interactions (e.g., hydrogen bonding, electrostatic attraction or covalent bonding). Surprisingly, an extremely low amount (0.05-0.30 wt%) of GO can remarkably affect the architecture of hydrogel networks, leading to the formation of macroporous composite hydrogels. On the whole, the GO-based polymer composite hydrogels possess both macroporous structures (10-100 mm) and enhanced mechanical performance, yet can still retain the similar swelling properties of their parent polymeric hydrogel. Therefore, this study provides a simple route for fabricating porous hydrogels, which could find some potential applications in wastewater treatment or biomedical engineering.
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