Journal
RSC ADVANCES
Volume 6, Issue 79, Pages 75478-75481Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra17664j
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Funding
- Basic Science Research Program through National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [NRF-2013R1A1A1058839]
- Incheon National University Research Grant
- National Research Foundation of Korea [2013R1A1A1058839] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A novel porphyrin and pyrene-based conjugated microporous polymer (Por-Py-CMP) was synthesized via Sonogashira-Hagihara cross coupling reaction. It exhibited a high Brunauer-Emmett-Teller specific surface area (1014 m(2) g(-1)) and high pore volume (0.81 cm(3) g(-1)). Por-Py-CMP demonstrated an excellent capacity for capturing carbon dioxide (13.2 wt%) at 273 K and 1 bar, and an outstanding ability to uptake iodine. It also showed high efficiency for singlet oxygen generation.
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