Journal
RSC ADVANCES
Volume 6, Issue 31, Pages 25986-25991Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra01487a
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Funding
- National Natural Science Foundation of China (NSFC) [21302061, 51373068]
- Jilin Province Science & Technology Development Program [20140520084JH]
- China Postdoctoral Science Foundation [2013T60318, 2012M510130]
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A sterically hindered silyl ether substituted quinacridone was successfully synthesized and its aggregation behaviors in different solvents were studied. It was demonstrated that the aggregate system of t-butyldiphenylsilyl ether substituted quinacridone in tetrahydrofuran was very stable and its aggregation-state could be tunable by fluoride-ion induced intermolecular force (e.g. hydrogen bonding and pi-pi stacking interactions) destructions and a chemical bond cleavage. The two aggregation-state changes of the system could be applied for a new dual guaranteed strategy for real-time naked-eye detection of fluoride-ions, which could provide assurance for both rapid responsive time and extraordinary selectivity.
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