Journal
RSC ADVANCES
Volume 6, Issue 30, Pages 25401-25408Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra02893d
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Funding
- National Natural Science Foundation of China [51473176, 91323301, 61475164, 61205194, 61275171, 91123032, 51003113]
- National Basic Research Program of China [2010CB934103]
- CAS-JSPS Joint Research Project [GJHZ1411]
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PMMA-SH/CdSe-Au nanocomposite thin films have been constructed by a layer-by-layer (LBL) assembly method. The LBL assembly process is carried out in a nonpolar solvent by the combination of photopolymerization and adsorption of CdSe-Au nanoparticles. Absorption spectra suggest that the LBL assembly is performed in a stepwise and uniform way. The optical, morphological, thermal, and optical limiting properties of the resultant PMMA-SH/CdSe-Au nanocomposite thin films are characterized by transmission, TEM, TGA and laser measurements. The LBL assembled PMMA-SH/CdSe-Au nanocomposite thin films exhibit good thermal stability, transparency, and optical limiting response to a 532 nm pulsed laser. The optical limiting threshold of the PMMA-SH/CdSe-Au nanocomposite thin film is 13 J cm(-2). This study provides a robust and efficient strategy for fabricating transparent polymeric thin films with laser optical limiting property.
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