Journal
RSC ADVANCES
Volume 6, Issue 23, Pages 19571-19575Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra00249h
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Funding
- National Natural Science Foundation of China [81473096]
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The discovery and development of a general method for the one-pot synthesis of substituted phenanthridines is presented. In the presence of Pd(PPh3)(4), accessible precursors undergo a Suzuki cross-coupling reaction with 2-(Boc-amino)benzeneboronic acid pinacol ester and then spontaneously undergo deprotection and intramolecular condensation to form the corresponding phenanthridines in one step. This reaction has a wide range of substrates with various functional groups, and the corresponding products have been obtained in good yields.
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