Journal
NPG ASIA MATERIALS
Volume 8, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/am.2016.17
Keywords
-
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [24102012, 2401]
- Frontier Chemistry Center Akira Suzuki 'Laboratories for Future Creation' Project
- Ministry of Education, Culture, Sports Science and Technology through Program for Leading Graduate Schools (Hokkaido University 'Ambitious Leader's Program')
- Grants-in-Aid for Scientific Research [15H00733] Funding Source: KAKEN
Ask authors/readers for more resources
The chiral nonanuclear Tb(III) clusters [Tb-9(sal-(R)-Bt)(16)(mu-OH)(10)]+[NO3]-(Tb-(R)-Bt: sal-(R)-Bt=(R)-2-butyl salicylate) and [Tb9 (sal-(S)-Bt)(16)(mu-OH)(10)](+)[NO3](-)(Tb-(S)-Bt: sal-(S)-Bt=(S)-2-butyl salicylate) were found to exhibit a unique magneto-optical property: the Faraday effect. The clusters were composed of 9 Tb(III) ions bridged by 10 mu-OHs and 16 chiral salicylic acid esters. The Faraday rotation angle of Tb-(R)-Bt was greater than that of Tb-(S)-Bt, indicating that the Faraday effect was affected by the chirality of the Tb(III) clusters. The chiroptical properties of the Tb(III) clusters were estimated using circular dichroism and circularly polarized luminescence. In this study, a new finding concerning chiral magneto-optical properties was investigated.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available