4.6 Article

A novel hollow capsule-like recyclable functional ZnO/C/Fe3O4 endowed with three-dimensional oriented recognition ability for selectively photodegrading danofloxacin mesylate

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 6, Issue 17, Pages 6513-6524

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cy00927a

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Funding

  1. National Natural Science Foundation of China [21306068, 21407064, 21546013]
  2. Natural Science Foundation of Jiangsu Province [BK20130487, BK20140532, BK20150536]
  3. Postdoctoral Science Foundation of Jiangsu Province [1501102B]

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A novel hollow capsule-like recyclable functional ZnO/C/Fe3O4 was synthesized by employing the convenient and mild sol-gel method combined with the surface imprinting technique, which possessed good light response ability, superior magnetic separation performance and excellent reproducibility. This as-prepared functional ZnO/C/Fe3O4 was proved to not only exhibit high photocatalytic activity but also possess a strong three-dimensional oriented ability to selectively recognize and photodegrade danofloxacin mesylate. Through getting insight into the mechanism, we can confirm that in this photocatalytic reaction, h(+) and OH play major roles compared with O-2(-) . This work not only puts forward a novel design idea of functional semiconductor materials but also is expected to be widely applied to the oriented recognition and removal of a target substance according to the practical requirement.

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