4.6 Article

Palladium-catalyzed alkoxycarbonylation of aryl halides with phenols employing formic acid as the CO source

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 6, Issue 9, Pages 3099-3107

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy01957e

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Funding

  1. NSFC [21472174]
  2. Education Department of Zhejiang Province [Y201432060]
  3. Zhejiang Sci-Tech University [1206838-Y, 14062015-Y]

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An efficient palladium-catalyzed alkoxycarbonylation of aryl halides with phenols has been developed. Various aryl benzoates have been isolated in good to excellent yields with formic acid as the CO source. The reaction proceeds smoothly under mild conditions and good functional group tolerance was observed.

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