Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 6, Issue 9, Pages 2892-2896Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cy00415f
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Funding
- DST, New Delhi, India [SR/S1/OC-33/2008]
- CSIR, New Delhi, India
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A novel contrast in palladium and copper catalysis is revealed to form products of different chemotypes resulting in a phenazine to azoarene twist through an altered mechanistic pathway (from non-radical C-H activation mode of C-N coupling to radical N-N coupling) during the oxidative self-coupling of anilines catalysed by Pd-Ag and Cu-Ag nanoclusters.
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