4.6 Article

Catalytic oxidation of methyl bromide using ruthenium-based catalysts

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 6, Issue 12, Pages 4337-4344

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy01900a

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Funding

  1. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB05050100]
  2. National Natural Science Foundation of China [21207132]

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Ruthenium-based catalysts Ru/TiO2, Ru/SiO2, Ru/gamma-Al2O3, and Ru/ZrO2 were prepared and evaluated for CH3Br oxidation, and Ru/TiO2 showed better catalytic performance than the other samples. The product yields and selectivities were also studied. The thermal stability was examined with a 48 h on-stream test. The influence of water vapor on the catalytic oxidation of CH3Br was studied at 210 degrees C and 230 degrees C, and it was found that the inhibition effect weakened with the increase in temperature. Additionally, Ru/TiO2 was also employed in the catalytic oxidation of CO, benzene, methyl acetate, and multi-pollutants of simulated PTA offgas.

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