4.8 Article

Ultrathin Surface Coating Enables the Stable Sodium Metal Anode

Journal

ADVANCED ENERGY MATERIALS
Volume 7, Issue 2, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201601526

Keywords

Al2O3; artificial solid electrolyte interphase; coating; high stability; low temperature PEALD; Na metal anodes; Na-ion-batteries

Funding

  1. Nanostructures for Electrical Energy Storage (NEES), an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Basic Energy Sciences [DESC0001160]
  2. Maryland Nanocenter and its Fablab
  3. AIMLab

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A stable Na metal anodeis is reported by forming an artificial solid electrolyte interphase via a low-temperature plasma-enhanced atomic layer deposition technology. It is discovered that an ultrathin layer of Al2O3 layer (2.8 nm) can protect Na metal from electrolyte decomposition, prevent 3D dendrite formation, and significantly enhance its cycle stability in a carbonate-based electrolyte.

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