Journal
ADVANCED ENERGY MATERIALS
Volume 6, Issue 7, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201501717
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Funding
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [NRF-2012M1A2A2671807]
- Ministry of Trade, Industry Energy (MOTIE)
- Korea Institute for Advancement of Technology (KIAT) [R0003399]
- Converging Research Center Program through the Ministry of Science, ICT and Future Planning, Korea [NRF2014M1A7A1A01030128]
- Global Frontier R&D Program on Center for Hybrid Interface Materials (HIM) - Ministry of Science, ICT & Future Planning [2013-073298, 2013M3A6B1078872]
- National Research Foundation of Korea [2013M3A6B1078872] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The surface framework of LiCoO2 is modified through a surface treatment called phosphidation, which suppressed the unwanted phase transition occurring above 4.2 V. The surface instability of LiCoO2 toward organic electrolytes is simultaneously improved by changing its surface structure from an O-2-based framework to a PO4-based framework that can protect against HF attack during cycling. Phosphidated LiCoO2 is successfully synthesized that showed greater stability in its bulk and surface structures. The phosphidated form enables faster Li+ diffusion and prevents irreversible phase transitions, especially when charged above 4.2 V, and consequently demonstrates excellent cycling performance and rate capabilities. The improved kinetics and stability resulting from phosphidation make LiCoO2 highly suitable as a high-voltage cathode material for use in lithium ion batteries.
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