Journal
ACS CATALYSIS
Volume 6, Issue 9, Pages 5904-5907Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b01636
Keywords
Achmatowicz reaction; biocatalysis; hypohalogenites; oxidation; peroxidase
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Funding
- European Union [KBBE-2013-7-613549]
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A catalytic, enzyme-initiated (aza-) Achmatowicz reaction is presented. The involvement of a robust vanadium-dependent peroxidase from Curvularia inaequalis allows the simple use of H2O2 and catalytic amounts of bromide.
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