Journal
ACS CATALYSIS
Volume 6, Issue 10, Pages 6408-6412Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b01845
Keywords
palladium catalysis; vinyl epoxide; vinyl cyclopropane; para-quinone methide; [3+2] cycloaddition
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Funding
- Singapore National Research Foundation [R-143-000-477-281]
- Ministry of Education of Singapore [R-143-000-613-112]
- National University of Singapore [R-143-000-605-112]
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Here, we present an unprecedented formal [3 + 2] cycloaddition of para-quinone methides with vinyl epoxides/cyclopropanes to deliver a wide range of spiro[4.5]decanes in high efficiency and stereoselectivity. The commercial availability of the catalysts and reagents, together with the convenient procedure, makes it an attractive method in asymmetric synthesis.
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