Journal
ACS CATALYSIS
Volume 6, Issue 7, Pages 4438-4442Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b00801
Keywords
nickel-catalyzed alkylation; B-alkyl-9-BBNs; C-O bond activation
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Funding
- China Scholarship Council
- DAAD
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A new and efficient nickel-catalyzed alkylation of C-Ar-O electrophiles with B-alkyl-9-BBNs is described. The transformation is characterized by its functional group tolerance and provides a practical and versatile access to various C-sp2-C-sp3 bonds through C-sp2-O substitution, without the restriction of beta-hydride elimination. Moreover, the advantage of the newly developed method was demonstrated in a selective and sequential C-O bond activation process.
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