4.8 Article

Divergent Synthesis of Carbo- and Heterocycles via Gold-Catalyzed Reactions

Journal

ACS CATALYSIS
Volume 6, Issue 4, Pages 2515-2524

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b00048

Keywords

gold catalysis; carborycles; heterocycles; cycloisomerization; cycloaddition

Funding

  1. National Basic Research Program of China (973) [2015CB856603]
  2. National Natural Science Foundation of China [21572052, 21421091, 21372250, 21361140350, 21372241, 21302203, 20672127, 21121062, 20732008, 20472096]

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The latest advances in the field of gold catalyzed divergent synthesis of carbo- and heterocycles are highlighted in this Perspective. These gold-catalyzed reactions, which can provide structurally novel carbo- and heterocycles, were achieved with good product selectivities, through subtle choice of substrates, catalysts, ligands, and counterions. The related reaction mechanisms are also discussed.

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