Journal
ACS CATALYSIS
Volume 6, Issue 6, Pages 3569-3574Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b00404
Keywords
metal organic frameworks; hydrogenation; catalysis; rhodium; size exclusion
Categories
Funding
- U.S. Department of Energy (Office of Basic Energy Sciences) [DE-FG02-08ER 15997]
Ask authors/readers for more resources
The cationic rhodium complexes (dppe)Rh(COD)BF4 and (MeCN)2Rh(COD)BF4 have been supported in metal-organic frameworks bearing anionic nodes (ZJU-28) and anionic linkers (MIL-101-SO3) via ion exchange. These MOF-supported Rh species serve as recyclable catalysts for the hydrogenation of both the terminal alkene substrate 1-octene and the internal alkene substrate 2,3-dimethylbutene. The nature of the MOF support impacts various aspects of catalysis, including: (i) the rate of 1-octene hydrogenation, (ii) the activity and recyclability of the catalyst in 2,3-dimethylbutene hydrogenation, and (iii) the size selectivity of hydrogenation with alkene substrates appended to calixarenes.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available