Journal
ACS CATALYSIS
Volume 6, Issue 6, Pages 3665-3669Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b01019
Keywords
amide; deoxygenative hydrogenation; boron Lewis acid; iridium pincer complex; homogeneous catalysis
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Funding
- National Natural Science Foundation of China
- National Basic Research Program of China [2012CB821600]
- 111 project of the Ministry of Education of China [B06005]
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The iridium-catalyzed highly chemoselective hydrogenation of amides to amines has been developed. Using a well-defined iridium catalyst bearing a P(O)C(O)P pincer ligand combined with B(C6F5)(3), the C O cleavage products are formed under mild reaction conditions. The reaction provides a new method for the preparation of amines from amides in good yield with high selectivity.
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