Journal
ACS CATALYSIS
Volume 6, Issue 12, Pages 8004-8008Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b02786
Keywords
1,4-dihydropyridines; nickel catalysis; photocatalysis; nickel/photoredox dual catalysis; oxidative deformylation
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Funding
- National Institutes of Health [NIGMS 1 R01 GM113878]
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A Ni/photoredox dual catalytic cross-coupling is disclosed in which a diverse range of (hetero)aryl bromides are used as electrophiles, with 1,4-dihydropyridines serving as precursors to C-sp(3)-centered alkyl radical coupling partners. The reported method is characterized by its extremely mild reaction conditions, enabling access to underexplored cores.
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