Journal
ACS CATALYSIS
Volume 6, Issue 8, Pages 4814-4858Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b01001
Keywords
chiral monophosphorus ligands; asymmetric allylic substitution; asymmetric dearomative atylation; asymmetric cross-coupling; asymmetric C H bond functionalization; asymmetric addition; asymmetric hydrogenation; asymmetric organocatalysis
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Chiral monophosphorus ligands are playing an important role for the recent advances in asymmetric catalysis. This review summarizes the latest progress in various asymmetric catalytic reactions with the employment of chiral monophosphorus ligands including asymmetric allylic substitution, asymmetric dearomative arylation, asymmetric Heck reaction, asymmetric cross-coupling, asymmetric C-H bond functionalization, asymmetric coupling of pi systems, asymmetric addition, asymmetric hydrogenation, and asymmetric organocatalytic reactions. The new reactivity, selectivity, and reaction mechanism enabled by these chiral monophosphorus ligands are discussed.
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