Journal
ACS CATALYSIS
Volume 6, Issue 7, Pages 4110-4116Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b00530
Keywords
gold nanoparticle; nitrobenzene hydrogenation; high activity; anatase; adsorption; selectivity
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Funding
- National Science Foundation [DMREF CHE-1434378]
- National Natural Science Foundation of China [21273197, U1462202, 21403192]
- Direct For Mathematical & Physical Scien [1434378] Funding Source: National Science Foundation
- Division Of Chemistry [1434378] Funding Source: National Science Foundation
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Highly selective hydrogenation of molecules containing more than one reducible group is always challenging. Here we report an efficient strategy for rational preparation of highly selective gold-based catalysts in the hydrogenation of substituted nitroarenes by positioning gold nanoparticles on the edge/corner sites of anatase. Mechanistic studies reveal that the catalyst with gold nanoparticles on the edge/corner sites of anatase could form unique sites for selective adsorption and activation of nitro groups, thus leading to high activity and selectivity. This strategy for preparation of supported gold catalysts opens a new door for the design of highly efficient heterogeneous catalysts in the future.
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