Journal
ACS CATALYSIS
Volume 6, Issue 8, Pages 5319-5344Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b01496
Keywords
sulfur-containing tetrasubstituted carbon stereocenters; enantioselective C-S bond-forming reactions; S-containing synthons; organocatalysis; metal catalysis
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Funding
- 973 program [2015CB856600]
- NSFC [21472049, 21502053]
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Sulfur-containing tetrasubstituted carbon stereo centers are widely present in natural products, drugs, and biologically active compounds. Catalytic enantioselective construction of such fully substituted carbon stereocenters is a current research interest, with four major synthetic strategies being developed. This review summarizes the advances in this field, discusses in detail the advantages and limitation of each synthetic strategy, and outlines the synthetic opportunities still open for development.
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