Journal
ACS CATALYSIS
Volume 6, Issue 11, Pages 7528-7535Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b02333
Keywords
catalysis; reversible; shuttle catalysis; alkene; isodesmic reactions
Categories
Funding
- Max-Planck-Society/Max-Planck-Institut fur Kohlenforschung
- Leverhulme Trust
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In this Perspective, we describe an emerging type of catalysis that enables the catalytic reversible transfer of chemical entities beyond the well-established transfer hydrogenation reactions. Shuttle catalysis facilitates the transfer of small molecules (e.g., CO, HCN) or reactive intermediates between two substrates in an isodesmic process. In many cases, these often safer processes provide unprecedented synthetic flexibility and complement other catalytic bond-forming and bond-breaking reactions.
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