Journal
ACS CATALYSIS
Volume 6, Issue 6, Pages 3452-3456Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b00777
Keywords
palladium; tandem reaction; perfluoroalkylation; homogenous catalysis; alkynes
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Funding
- Polish National Science Centre [DEC-2013/11/D/ST5/02979]
- Polish Ministry of Science and Higher Education
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A three-component Pd-catalyzed difunctionalization of internal and terminal alkynes with iodoperfluoroalkanes and boronic acids is reported here. Under low catalyst loading and mild reaction conditions, perfluoroalkylated tri- and tetrasubstituted olefins were obtained in very good yields and in excellent regio- and stereoselectivities.
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