Journal
ACS CATALYSIS
Volume 6, Issue 3, Pages 1389-1407Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02386
Keywords
EDA complexes; CT complexes; charge-transfer band; photochemistry; visible light; organic synthesis
Categories
Funding
- CAPES
- CNPq [158438/2012-4, 475448/2013-8, 458416/2014-2]
- FAPESP [2014/50249-8, 2015/17141-1, 2013/09680-4]
- CNPq (INCT-Catalise)
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In the past decades, the physicochemical properties of electron donor acceptor, EDA, complexes (also called charge-transfer, CT, complexes) have been extensively studied, although their synthetic applications have been somewhat limited. However, in recent years, this scenario has started to change as an increasing number of examples have been reported. In this regard, this review aims to present and discuss the main aspects associated with the physicochemical properties of these complexes and a selection of synthetic photochemical applications in organic chemistry.
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