4.8 Article

Lactic Acid from Glycerol by Ethylene-Stabilized Platinum-Nanoparticles

Journal

ACS CATALYSIS
Volume 6, Issue 3, Pages 1671-1674

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02914

Keywords

platinum nanoparticles; metal vapor synthesis; glycerol; lactic acid; ethylene; carbonaceous supports

Funding

  1. MIUR-Italy (FIRB) [RBFR10BF5 V]

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Small-sized Pt-nanoparticles (NPs) of 1.5 nm, generated by metal vapor synthesis, and supported onto Ketjenblack proved to be the first example of a heterogeneous monometallic Pt-NP-based catalyst, which was stabilized by ethylene during conversion of glycerol to lactate (LA). A LA chemoselectivity of 95% was obtained in three consecutive catalytic runs.

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