Journal
NATURE COMMUNICATIONS
Volume 7, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/ncomms13912
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Funding
- Center for Optical and Electron Microscopy of ETH Zurich (ScopeM)
- ETH Zurich
- Swiss National Science Foundation [200020_146509]
- Swiss Competence Center for Energy Research (SCCER-Capacity Area A3: Minimization of energy demand)
- Swiss National Science Foundation (SNF) [200020_146509] Funding Source: Swiss National Science Foundation (SNF)
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Shaping ceramics into complex and intricate geometries using cost-effective processes is desirable in many applications but still remains an open challenge. Inspired by plant seed dispersal units that self-fold on differential swelling, we demonstrate that self-shaping can be implemented in ceramics by programming the material's microstructure to undergo local anisotropic shrinkage during heat treatment. Such microstructural design is achieved by magnetically aligning functionalized ceramic platelets in a liquid ceramic suspension, subsequently consolidated through an established enzyme-catalysed reaction. By fabricating alumina compacts exhibiting bio-inspired bilayer architectures, we achieve deliberate control over shape change during the sintering step. Bending, twisting or combinations of these two basic movements can be successfully programmed to obtain a myriad of complex shapes. The simplicity and the universality of such a bottom-up shaping method makes it attractive for applications that would benefit from low-waste ceramic fabrication, temperature-resistant interlocking structures or unusual geometries not accessible using conventional top-down manufacturing.
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