Journal
CHEMICAL SCIENCE
Volume 7, Issue 10, Pages 6492-6498Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6sc00490c
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Funding
- DTRA [HDTRA1-14-1-0014]
- NSF [DGE-1324585]
- NSF-NSEC
- NSF-MRSEC
- Keck Foundation
- state of Illinois
- NU
- MRSEC program of the National Science Foundation [DMR-1121262]
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UiO-66 and analogues were successfully tailored to chemoselectively capture As-V oxyanions at the hydroxylated node and neutral As-III species with the thiolated organic linkers. More efficient and faster uptake can be achieved with increasing defect densities, increasing pore aperture sizes, and decreasing particle sizes.
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