Journal
TETRAHEDRON LETTERS
Volume 57, Issue 42, Pages 4737-4741Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.09.035
Keywords
Molecular switch; Stimuli responsive; Aromatic amide; pH-dependent
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Funding
- JSPS KAKENHI [26460154]
- Hoansha Foundation
- Grants-in-Aid for Scientific Research [26460154] Funding Source: KAKEN
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Nuclear magnetic resonance (NMR) studies of acid-induced conformational switching (trans/cis isomerization) of N,N-diarylamides bearing a pyridine moiety indicated that the trans/cis conformational preference of these amides is dependent on the relative Pi-electron densities of the two N-aromatic parts, and can be controlled by protonation or deprotonation of pyridine. (C) 2016 Elsevier Ltd. All rights reserved.
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