4.4 Article

One-pot epoxidation of alkenes using aerobic photoperoxidation of toluenes

Journal

TETRAHEDRON LETTERS
Volume 57, Issue 2, Pages 230-232

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.12.027

Keywords

Epoxidation; Photooxidation; Anthraquinone; Green chemistry

Funding

  1. Gifu Pharmaceutical University
  2. Asahi Glass Foundation

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We developed an aerobic photooxidative synthesis of peroxybenzoic acids from toluenes using anthra-quinone-2-carboxylic acid (AQN-2-CO2H) as a photocatalyst. We also found a one-pot epoxidation reaction of alkenes using 4-tert-butylperoxybenzoic acid produced in situ by aerobic photooxidative synthesis. (C) 2015 Elsevier Ltd. All rights reserved.

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