Journal
TETRAHEDRON LETTERS
Volume 57, Issue 2, Pages 192-195Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2015.11.093
Keywords
Triphenyltin chloride; Aryl halide; Cu(OAc)(2); Catalyst; Sulfide
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Funding
- Iran National Science Foundation (INSF)
- University of Kurdistan Research Councils
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A novel method for the Cu(OAc)(2) catalyzed synthesis of unsymmetrical sulfides from triphenyltin chloride and aryl halides using S-8 as the sulfur source in PEG200 at 60-80 degrees C is reported. Triphenyltin chloride is capable of delivering all of its phenyl groups to the product. Also, the copper catalyzed synthesis of symmetrical diaryl sulfides from aryl halides using S-8 is described. (C) 2015 Elsevier Ltd. All rights reserved.
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