4.4 Article

Rhodamine-naphthalene conjugate as a novel ratiometric fluorescent probe for recognition of Al3+

Journal

TETRAHEDRON LETTERS
Volume 57, Issue 17, Pages 1935-1939

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.03.074

Keywords

Fluorescent sensor; Rhodamine/naphthalene; Al3+; Ratiometric; FRET/ICT

Funding

  1. National Natural Science Foundation of China [81171337]
  2. Gansu NSF [1308RJZA115]

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In this study, a novel chemosensor (HL) for Al3+ which contains rhodamine and naphthalene moieties has been designed and synthesized. In the presence of Al3+, the receptor exhibited a strong, increasing fluorescent emission centered at 550 nm at the expense of the fluorescent emission of HI-centered at 520 nm. We proposed that the addition of Al3+ triggered intramolecular fluorescence resonance energy transfer (FRET) from naphthalene to Rhodamine 6G. (C) 2016 Elsevier Ltd. All rights reserved.

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