4.4 Article

Silver-catalyzed organic reactions of isocyanides

Journal

TETRAHEDRON LETTERS
Volume 57, Issue 51, Pages 5730-5741

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.11.005

Keywords

Isocyanides; Silver catalysis; Cycloadditions; Cross-couplings

Funding

  1. NSFC [21522202, 21502017, 21372038]
  2. Ministry of Education of the People's Republic of China [NCET-13-0714]
  3. Jilin Provincial Research Foundation for the Basic Research [20140519008JH]
  4. Fundamental Research Funds for Central Universities [2412015BJ005, 2412015KJ013, 2412016KJ040]
  5. Jilin Province Key Laboratory of Organic Functional Molecular Design Synthesis [130028658]

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The combined chemistry of silver and isocyanides is unique in performance, proved with the number of recent achievements. With the aim of triggering further research in this field, this review assembles and comprehensively summarizes the silver-based reactions of isocyanides. In this review, we especially emphasize the uniqueness of silver catalysis in the activation of isocyanides, the reaction selectivity, and the mechanistic description. (C) 2016 Elsevier Ltd. All rights reserved.

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