4.4 Article

A novel urea-derived fluorescent sensor for highly selective and sensitive detection of Fe3+

Journal

TETRAHEDRON LETTERS
Volume 57, Issue 30, Pages 3407-3411

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.06.089

Keywords

Fluorescent sensor; Urea derivative; Metal ion; Fe3+; Quenching

Funding

  1. National Natural Science Foundation of China [21376125]
  2. Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province

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A novel urea-derived fluorescent sensor MDSU for Fe3+ was designed and synthesized. Its sensing behavior to metal ions was investigated by absorption and fluorescence spectra. In DMSO/H2O (1:1, v/v) solution, sensor MDSU showed a highly selective and sensitive recognition to Fe3+ over other competitive metal ions. This sensor formed a 1:1 complex with Fe3+ and displayed fluorescence quenching. Moreover, sensor MDSU can rapidly detect Fe3+ in real time with a lower detection limit of 1.816 x 10(-7) M. (C) 2016 Elsevier Ltd. All rights reserved.

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