Journal
TETRAHEDRON LETTERS
Volume 57, Issue 27-28, Pages 3050-3052Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.06.011
Keywords
Cyclobutanone; [4+2] cycloaddition; Quinoline; Pyridine; Isoquinoline
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Funding
- JSPS KAKENHI Grant [15K07855]
- Grants-in-Aid for Scientific Research [15K07855] Funding Source: KAKEN
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3-Ethoxycyclobutanones reacted with pyridines, quinolines, and isoquinolines to give the corresponding formal [4+2] cycloadducts, 9a-hydro-2H-quinolizin-2-one derivatives, by using Me3SiOTf in acetonitrile. Cycloaddition of 3-ethoxy-2-monoalkylcyclobutanones to 5-nitroquinoline or 4-cyanopyridine proceeded stereoselectively. (C) 2016 Elsevier Ltd. All rights reserved.
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