4.4 Article

Chemoselective Cu(I) catalyzed bis(pinacolato)diboron conjugate addition and reduction onto α,β-unsaturated carbonyl compounds

Journal

TETRAHEDRON LETTERS
Volume 57, Issue 24, Pages 2587-2590

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.04.094

Keywords

Bis(pinacolato)diboron; Ligand-free; Conjugate addition; Reduction; alpha,beta-Unsaturated carbonyl compounds

Funding

  1. National High Technology Research and Development Program of China [2007AA02Z301]
  2. Natural Science Foundation of Jiangsu Province [BK20141257]
  3. Natural Science Foundation of Yancheng Teachers University [14YCKL001]
  4. Fundamental Research Funds for Central University [WY111307]

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Ligand-free CuI-catalyzed bis(pinacolato)diboron (B-2(pin)(2)) conjugate addition and reduction onto alpha,beta-unsaturated carbonyl compounds in moderate to excellent yields has been demonstrated. (C) 2016 Elsevier Ltd. All rights reserved.

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