Journal
TETRAHEDRON LETTERS
Volume 57, Issue 21, Pages 2222-2226Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.04.009
Keywords
Alkylation; Tertiary amines; C-N bond cleavage; P(O)-OH compounds
Categories
Funding
- NSFC [21273067, 21476065]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1238]
- Fundamental Research Funds for the Central Universities (Hunan University)
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Together with a base, dibromomethane enables the efficient synthesis of a broad range of functionalized phosphinates, phosphonates, and phosphates from P(O)-OH compounds and commercially available amines via C-N bond cleavage, affording the corresponding products in moderate to good yields. (C) 2016 Elsevier Ltd. All rights reserved.
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