Journal
TETRAHEDRON LETTERS
Volume 57, Issue 22, Pages 2462-2464Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.04.095
Keywords
Radical; Bromodifluoromethylation; Benzofuran; Heteroaromatics; Fluoroalkylation
Categories
Funding
- National Natural Science Foundation of China [21272036, 21332010, 21421002]
- National Basic Research Program of China [2012CB21600]
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The bromodifluoromethylation of heteroaromatics (benzofuran, benzo[b]thiophene, and 2H-chromen-2-one) with sodium bromodifluoromethanesulfinate (BrCF2SO2Na) was developed. This reaction proceeded smoothly at room temperature to afford the bromodifluoromethylated products in moderate to high yields. (C) 2016 Elsevier Ltd. All rights reserved.
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