Journal
TETRAHEDRON LETTERS
Volume 57, Issue 29, Pages 3063-3066Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.05.038
Keywords
Pd catalyzed; Heteroaryl boronic acids; C-P coupling
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Funding
- Natural Science Foundation of China [20772114, 21172200]
- Research Program of Fundamental and Advanced Technology of Henan Province [122300413203]
- Technology Research and Development Funds of Zhengzhou [141PRCYY516]
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We report herein a novel protocol to construct C-P bond from heteroaryl boronic acid with H-phosphonate diester under Pd-Ag catalyzed system without addition of base. This method, directly using commercial available heteroaryl boronic acid as the starting material, provides a new way to synthesize a variety of useful heteroaryl phosphonates. (C) 2016 Elsevier Ltd. All rights reserved.
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