Journal
TETRAHEDRON LETTERS
Volume 57, Issue 39, Pages 4345-4347Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.08.025
Keywords
Palladium catalyzed; Carbometalation; Hexafluorobut-2-yne; Boronic acid; Synthetic method
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Funding
- National Natural Science Foundation of China [21403163, 21503610, 21327011]
- Natural Science Basic Research Plan in Shaanxi Province of China [2014JQ2062]
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The Pd(0) catalyzed one-pot mono and difunctionalization of hexafluorobut-2-yne is investigated. Styrenes and stilbenes can be obtained in high stereoselectivity by carbopalladation of phenylboronic acids and iodide benzenes. The reactions afford a facile access to a broad scope with good functional compatibility. (C) 2016 Elsevier Ltd. All rights reserved.
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