Journal
TETRAHEDRON LETTERS
Volume 57, Issue 50, Pages 5519-5539Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2016.11.007
Keywords
Domino reactions; Natural products; Oxa-Michael addition; Synthetic strategy; Total synthesis
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Funding
- Zhejiang Natural Science Fund for Distinguished Young Scholars [LR16B020001]
- National Natural Science Foundation of China [21622205, 21472167]
- Fundamental Research Funds for the Central Universities [2016QNA3010]
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The strategy of employing oxa-Michael reaction in today's organic synthesis appears to be a big success due to its high efficiency in the construction of C-O bonds. In this digest, recent advances of its application in the total synthesis of representative oxygen-containing natural products, involving macrolides, terpenoids, chromanones and chromanes, polyoxygenated molecules and alkaloids et al. are discussed, with the aim of providing a complement to existing reviews. (C) 2016 Elsevier Ltd. All rights reserved.
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